This paper provides a basic introduction to the principles of ultraviolet photoelectron spectroscopy (UPS), ultraviolet photoelectron yield spectroscopy (PYS), and constant final state yield spectroscopy (CFS-YS) measurements. Different measurements were performed on HOPG, obtaining a series of electronic energy level parameters such as work functionΦ= 4.56 eV, valance band energy EVBM= 0.87 eV, and ionization energy Ith= 5.35 eV. It offers an initial understanding of the surface electronic structure via the ultraviolet photoelectron spectroscopy. The electronic structure of the material surface can be more finely characterized through the comparison and joint analysis of different measurement methods.